Problem

The gas-phase basicity of triphenylamine (876.4 kJ/mol) is less than that of triphenylph...

The gas-phase basicity of triphenylamine (876.4 kJ/mol) is less than that of triphenylphosphine (940.4 kJ/mol). Do you expect electronic or steric factors to contribute more to this difference? Explain. (Data from C. Laurence and J.-F. Gal, Lewis Basicity and Affinity Scales Data and Measurement , John Wiley and Sons, United Kingdom, 2010, p. 5 .)

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