Problem

When cis–OsO2F4 is dissolved in SbF5, the cation OsO2F3 + is formed. The 19F NMR spectru...

When cis–OsO2F4 is dissolved in SbF5, the cation OsO2F3 + is formed. The 19F NMR spectrum of this cation shows two resonances, a doublet and a triplet having relative intensities of 2:1. What is the most likely structure of this ion? What is its point group? (See W. J. Casteel, Jr., D. A. Dixon, H. P. A. Mercier, G. J. Schrobilgen, Inorg. Chem. , 1996 , 35 , 4310.)

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Solutions For Problems in Chapter 9