The exceptional stability of metal-organic frameworks containing Zr(IV) render them attractive for applications. One strategy for tuning MOF properties is to incorporate additional metals into the framework. Discuss the metalation options for MOF-525 and MOF-545 attempted in W. Morris, B. Volosskiy, S. Demir, F. Gándara, P. L. McGrier, H. Furukawa, D. Cascio, J. F. Stoddart, O. M. Yaghi, Inorg. Chem. , 2012 , 51 , 6443. Draw the structure of the linker that permits metal incorporation. How are MOF-525 and MOF-545 similar in their ability to be metalated? How are they different?
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