The electronic absorption spectra of a series of complexes of formula [DBSQ = 3,5-ditert-butyl-1,2-benzosemiquinone] show a single maximum in the visible spectrum. The absorption maxima for three of these complexes in benzene solution are shown; typical molar absorptivities are in the range of 5,000 to 6,000 L mol-1 cm-1 .
Are these bands more likely due to charge transfer to metal or charge transfer to ligand? Explain briefly. (See F. Hartl, A. Vlcek, Jr., Inorg. Chem ., 1996 , 35 , 1257.)
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