Problem

The absorption spectrum of the linear ion NiO22- has bands attributed to d–d transitions...

The absorption spectrum of the linear ion NiO₂²^- has bands attributed to d–d transitions at approximately 9,000 and 16,000 cm^-¹ .

a. Using the angular overlap model ( Chapter 10 ) , predict the expected splitting pattern of the d orbitals of nickel in this ion.

b. Account for the two absorption bands.

c. Calculate the approximate value of . (See M. A. Hitchman, H. Stratemeier, R. Hoppe, Inorg. Chem ., 1988 , 27 , 2506.)

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Solutions For Problems in Chapter 11

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