Construct the ions Re2Cl8 2- and Os2Cl8 2- (see Figure 15.7), and calculate and display their molecular orbitals. Compare these orbitals with Figure 15.8, focusing on the metal–metal bonds and on d-orbital interactions with the ligands, and classify orbitals involved in metal–metal bonding as How do your results compare with the quadruple and triple bonds reported respectively for these ions? (Depending on the software used, you may need to fix atoms in position before doing orbital calculations, especially for Re2Cl8 2-. Structural information on this ion can be found in F. A . Cotton, C. B. Harris, Inorg. Chem., 1965, 4, 330.)
We need at least 10 more requests to produce the solution.
0 / 10 have requested this problem solution
The more requests, the faster the answer.