Problem

Hydrides such as NaBH4 and LiAlH4 have been reacted with the complexes [(C5Me5)Fe(C6H6)]...

Hydrides such as NaBH4 and LiAlH4 have been reacted with the complexes [(C5Me5)Fe(C6H6)]+ , [(C5H5)Fe(CO)3]+ , and [(C5H5)Fe(CO)2(PPh3)]+ . (See P. Michaud, C. Lapinte, D. Astruc, Ann. N. Y. Acad. Sci. , 1983 , 415 , 97.) a. Show that these complexes are isolobal.

b. Predict the products of the reactions of these complexes with hydride reagents.

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Solutions For Problems in Chapter 15