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Problems are listed in approximate order of difficulty. A single dot (•) indicates straigh...

Problems are listed in approximate order of difficulty. A single dot (•) indicates straightforward problems involving just one main concept and sometimes requiring no more than substitution of numbers in the appropriate formula. Two dots (••) identify problems that are slightly more challenging and usually involve more than one concept. Three dots (•••) indicate problems that are distinctly more challenging, either because they are intrinsically difficult or involve lengthy calculations. Needless to say, these distinctions are hard to draw and are only approximate.

•• Consider a simple solid, such as aluminum, consisting of N identical atoms. Assume that the Einstein approximation correctly describes the vibrational motion of the atom. (a) Assume that the vibrational level spacing has the value ε = 0.037 eV (a typical value in a solid) and consider the probability that an atom of the solid is in its ground state. At what temperature is this probability equal to 0.1? (b) For a given N and ε, how high does the temperature have to be to ensure that effectively no atoms are in the ground state? Is this temperature achievable in an ordinary sample of a solid?

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