Of the two procedures just described, preparation and carboxylation of a Grignard reagent or formation and hydrolysis of a nitrile, only one is appropriate to each of the following conversions. Identify the correct procedure in each case, and specify why the other will fail.
(a) Bromobenzene→ benzoic acid
(b) 2-Chloroethanol →3-hydroxypropanoic acid
(c) tert-Butyl chloride →2,2-dimethylpropanoic acid
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