Problem

• Use the following data to estimate the dissociation energies of the three ionic molecule...

• Use the following data to estimate the dissociation energies of the three ionic molecules KI, NaBr, and LiF. (IE denotes ionization energy and EA electron affinity.) Compare your answers with the observed values given in the last column. Your answers should all be overestimates; explain why.

IE (eV)

EA (eV)

R0 (nm)

B (eV)

K: 4.34

I: 3.06

KI: 0.30

3.31

Na: 5.14

Br: 3.36

NaBr: 0.250

3.74

Li: 5.39

F: 3.40

LiF: 0.156

5.91

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