• The vibrational–rotational spectrum (12.35) of a diatomic molecule is in the infrared region. At low resolution it is seen as a single band centered on Eγ = ℏωc. The molecule LiBr shows a bright band in the IR region, centered at λ = 17.8 μm. Use this to find the force constant k for LiBr (treating the Br atom as fixed).
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