Assume the internal energy of an elastic fiber under tension (see Problem P6.16) is given by dU = T dS - . Obtain an expression for
and calculate the maximum nonexpansion work obtainable when a collagen fiber contracts from
to 10.0 cm at constant P and T. Assume other properties as described in Problem P6.16.
Reference Problem P6.16
Collagen is the most abundant protein in the mammalian body. It is a fibrous protein that serves to strengthen and support tissues. Suppose a collagen fiber can be stretched reversibly with a force constant of k = 10.0 N m-1 and that the force F (see Table 2.1) is given by When a collagen fiber is contracted reversibly, it absorbs heat qrev = 0.050 J . Calculate the change in the Helmholtz energy as the fiber contracts isothermally from to 0.10 m. Calculate also the reversible work performed wrev,ΔS , andΔ U. Assume that the temperature is constant at T = 310.
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