Values of A0CI for [Ni(OH2)6]2- and high-spin [Mn(OH2)6]3' have been evaluated spectroscopically as 8500 and 21 000 cm 1 respectively. Assuming thj these values also hold for the corresponding oxide lattices, predict whether NiHMn2n04 should have the normal or inverse spinel structure. What factor, might make your prediction unreliable?
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