The electronic absorption spectrum of [Co(OH2)6]2+ exhibits bands at 8100, 16000 and 19400 cm '.Assign these bands to electronic transitions. The value of Aucl for [Co(OH2)6]21 listed in Table 20.2 is 9300 cm-1. What value of AOCI would you obtain using the diagram in Fig. 20.23b? Why does the calculated value not match that in Table 20.2?
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