Problem

Heating with NaH in solution gives A , which has the empirical formula C7H6O2Fe. A react...

Heating with NaH in solution gives A , which has the empirical formula C7H6O2Fe. A reacts rapidly at room temperature to eliminate a colorless gas B , forming a purple-brown solid C having the empirical formula C7H5O2Fe. Treatment of C with iodine generates a brown solid D with the empirical formula C7H5O2FeI, which on treatment with TlC5H5 gives a solid E with the formula C12H10O2Fe. E , on heating, gives off a colorless gas, leaving an orange solid F with the formula C10H10Fe. Propose structural formulas for A through F .

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Solutions For Problems in Chapter 14