Problem

The reaction of V(CO)5(NO) with P(OCH3)3 to give V(CO)4[P(OCH3)3](NO) has the rate law...

The reaction of V(CO)5(NO) with P(OCH3)3 to give V(CO)4[P(OCH3)3](NO) has the rate law

a. Suggest a mechanism for this reaction consistent with the rate law.

b. One possible mechanism consistent with the last term in the rate includes a transition state of formula V(CO)5[P(OCH3)3](NO). Would this necessarily be a 20-electron species? Explain.

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Solutions For Problems in Chapter 14