Problem

Phase Changes (Section)(a) What is the significance of the critical pressure of a substanc...

Phase Changes (Section)

(a) What is the significance of the critical pressure of a substance? (b) What happens to the critical temperature of a series of compounds as the force of attraction between molecules increases? (c) Which of the substances listed in Table can be liquefied at the temperature of liquid nitrogen (-196 °C)?

Table Critical Temperatures and Pressures of Selected Substances

Substance

Critical Temperature (K)

Critical Pressure (atm)

Nitrogen, N2

126.1

33.5

Argon, Ar

150.9

48.0

Oxygen, O2

154.4

49.7

Methane, CH4

190.0

45.4

Carbon dioxide, CO2

304.3

73.0

Phosphine, PH3

324.4

64.5

Propane, CH3CH2CH3

370.0

42.0

Hydrogen sulfide, H2S

373.5

88.9

Ammonia, NH3

405.6

111.5

Water, H2O

647.6

217.7

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