Problem

Five isomeric alkanes (A–E) having the molecular formula C6H14 are each treated with Cl2 +...

Five isomeric alkanes (A–E) having the molecular formula C6H14 are each treated with Cl2 + hv to give alkyl halides having molecular formula C6H13Cl. A yields five constitutional isomers. B yields four constitutional isomers. C yields two constitutional isomers. D yields three constitutional isomers, two of which possess stereogenic centers. E yields three constitutional isomers, only one of which possesses a stereogenic center. Identify the structures of A–E.

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