Problem

(a) On being heated with potassium ethoxide in ethanol (70°C), the deuteriumlabeled alkyl...

(a) On being heated with potassium ethoxide in ethanol (70°C), the deuteriumlabeled alkyl bromide shown gave a mixture of 1-butene, cis 2 butene, and trans-2-butene. On the basis of your knowledge of the E2 mechanism, predict which alkene(s), if any, contained deuterium.


(b) The bromide shown in part (a) is the erythro diastereomer. How would the deuterium content of the alkenes formed by dehydrohalogenation of the threo diastereomer differ from those produced in part (a)?

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