The stepwise stability constants in aqueous solution at 25° C for the formation of the ions [M(en)(H2O)4]2+, [M(en)2(H2O)2]2+, and [M(en)3]2+ for copper and nickel are given in the table. Why is there such a difference in the third values? (Hint: Consider the special nature of d9 complexes.)
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