A possible geometry for an eight-coordinate complex ML8 might be a hexagonal bipyramid:
a. Predict the effect of the eight ligands on the energies of the d orbitals of a metal M, using the angular overlap model and assuming that the ligands are sigma donors only. [Note: To determine the values of you will need to add two more positions to Table 10.11 .]
b. Assign the symmetry labels of the d orbitals (labels of the irreducible representations).
c. Repeat the calculations in part a for a ligand that can act both as a donor and a π acceptor.
d. For this geometry, and assuming low spin, which dn configurations would be expected to give rise to Jahn–Teller distortions?
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