Write the structure of the carbinolamine intermediate and the imine product formed in the reaction of each of the following:
(a) Acetaldehyde and benzylamine, C6H5CH2NH2
(b) Benzaldehyde and butylamine, CH3CH2CH2CH2NH2
(c) Cyclohexanone and tert-butylamine, (CH3)3CNH2
(d) Acetophenone and cyclohexylamine,
Sample Solution The carbinolamine is formed by nucleophilic addition of the amine to the carbonyl group. Its dehydration gives the imine product.
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