(a) The reaction of CsF, 1205 and IF5 at 435 K leads to CS2.IOF5. When the amount of CsF is halved, the product is CslOF4. Write balanced equations for the reactions. Are they redox reactions?
(b) Using data in Fig. 17.14, calculate AG°(298 K) for the reaction:
4[C1O3]–(aq) ^ 3[C1O4]-(aq) + CP (aq)
Comment on the fact that the reaction does not occur al 298 K.
(c) Chlorine dioxide is the major bleaching agent in the pulp industry. While some statistics for bleaching agents list C1O2, others give NaC1O3 instead. Suggest reasons for this difference.
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