Problem

More Challenging Questions These questions require more thought and integrate several c...

More Challenging Questions

These questions require more thought and integrate several concepts.

Without consulting tables of ΔHf°, S°, or ΔGf° values, predict which of these reactions is

(i) always product-favored.

(ii) product-favored at low temperatures, but not productfavored at high temperatures.

(iii) not product-favored at low temperatures, but productfavored at high temperatures.

(iv) never product-favored.

(a) 2 NO2(g) → N2O4(g)

(b) C5H12(g) + 8 O2(g) → 5 CO2(g) + 6 H2O(g)

(c) P4(g) + 10 F2(g) → 4 PF5(g)

[Hint: Use the qualitative rules regarding bond enthalpies in Section 6.7 (p. 238) to predict the sign of ΔH°.]

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