Find f for the following systems and give a reasonable choice for the independent intensive variables: (a) a gaseous mixture of N2, H2, and NH3 with no catalyst present (so that the rate of reaction is zero); (b) a gaseous mixture of N2, H2, and NH3 with a catalyst present to establish reaction equilibrium;(c)the system of (b) with the added condition that all the N2 and H2 must come from the dissociation of the NH3; (d) A gas- phase mixture of N2 and N in reaction equilibrium with the condition that all the N comes from the dissociation of N2; (e) a system formed by heating pure CaCO3(s) to partially decompose it into CaO(s) and CO2(g), where, in addition, some of each of the solids CaCO3 and CaO has sublimed to vapor. (No CaO or CO, is added from the outside.)
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