Problem

The gas-phase decompositionis carried out in a constant-volume batch reactor. Runs I throu...

The gas-phase decomposition

is carried out in a constant-volume batch reactor. Runs I through 5 were carried out at 100°C, while run 6 was carried out at 100°C.

(a) From the data in Table PS-10, determine the reaction order and specific reaction rate constant.

(b) What is the activation energy for this reaction?

Run	Initial Concentration, CAO (gmol/L)	Half Life, t1/2 (min)
1	0.0250	4.1
2	0.0133	7.7
3	0.010	9.8
4	0.5	1.96
5	0.075	1.3
6	0.025	2.0

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