Problem

The liquid-phase reaction of methanol and triphenyl takes place in a batch reactor at 25°C...

The liquid-phase reaction of methanol and triphenyl takes place in a batch reactor at 25°C

For an equimolar feed the following concentration- time data was obtained for methanol:

CA (mol/dm3)

1.0

0.95

0.816

0.707

0.50

0.370

I (h)

0

0.278

1.389

2.78

8.33

16.66

The following concentration-time data were obtained for an initial methanol concentration 0.01 molldm3 and an initial triphenyl of 1.0 mol/dm3:

CA (mol/dm3)

0. 1

0.0847

0.0735

0.0526

0.0357

I (h)

0

1

2

5

10

(a) Determine the rate law and rate law parameters.

(b) If you were to take more data points, what would be the reasonable settings (e.g., CA0, CB0)? Why

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Solutions For Problems in Chapter 5