Problem

Draw closo-B6H62- (see Figure 15.12), and calculate its molecular orbitals. Identify and...

Draw closo-B6H62- (see Figure 15.12), and calculate its molecular orbitals. Identify and display the following:

a. The orbital having A1g symmetry resulting from overlap of p or hybrid orbitals pointing toward the center of the octahedron (see Figure 15.13).

b. Three orbitals having T1u symmetry involving pi interactions between sets of four boron p orbitals.

c. Three orbitals having T2g symmetry involving overlap of sets of four boron p orbitals within the same plane.

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Solutions For Problems in Chapter 15