Problem

Use Eq. (4.75) to show that dq = T dS +∑iµi dni for a one-phase closed system with P−V wor...

Use Eq. (4.75) to show that dq = T dS +∑iµi dni for a one-phase closed system with P−V work only in mechanical and thermal equilibrium. This expression gives dq during a chemical reaction. Since the reaction is irreversible, dq ≠ T dS.

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Solutions For Problems in Chapter 4