For the isoelectronic series [V(CO)6]-, Cr(CO)6, and [Mn(CO)6]+, would you expect the energy of metal to ligand charge-transfer bands to increase or decrease with increasing charge on the complex? Why? (See K. Pierloot, J. Verhulst, P. Verbeke, L. G. Vanquickenborne, Inorg. Chem ., 1989 , 28 , 3059.)
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