Problem

MnO4 - is a stronger oxidizing agent than ReO4 - . Both ions have charge-transfer bands;...

MnO4 - is a stronger oxidizing agent than ReO4 - . Both ions have charge-transfer bands; however, the chargetransfer band for ReO4- is in the ultraviolet, whereas the corresponding band for MnO4 - is responsible for its intensely purple color. Are the relative positions of the charge-transfer absorptions consistent with the oxidizing abilities of these ions? Explain.

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Solutions For Problems in Chapter 11