One isomer of [PdBr2(NH3)2] is unstable with respect to a second isomer, and the isomerization process can be followed by IR spectroscopy. The IR spectrum of the first isomer shows absorptions at 480 and 460 cm-1 assigned to v(PdN) modes. During gradually -1 isomerization, the band at 460 cm disappears and that at 480 cm' 1 shifts to 490 cm Rationalize these data.
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