A pH study using a glass electrode at 303 K for complex formation between Al3+ ions and [acac]– (Table) in aqueous solution gives values of logK1, logK2 and logK3 as 8.6, 7.9 and 5.8.
(a) To what equilibria do these values refer?
(b) Determine values for Δ G°1,(303 K), Δ G°2(303K) and Δ G°3(303 K) and comment on the relative ease with which successive ligand displacement reactions occur.
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