I is tertiary carbocation which is most stable already.
So, there will not be any rearrangement.
II is secondary carbocation and it can form tertiary carbocation.
So, it will rearrange.
III is secondary carbocation but its neighbour carbon also are secondary.
So, there will not be any rearrangement.
IV is primary carbocation and it can form tertiary carbocation.
So, it will rearrange.
Answer: c) II,IV
Which of the following carbocations are most likely to rearranger CHE CH3 CH3 © CH2 a)...
hich of the following carbocations are most likely to rearrange? CH3 CH3 CH₃ CH2 a) III, IV b) I, 11 c) II, IV d) I, IM
6. Which of the following carbocations would NOT be likely to undergo rearrangement? A) CH3CHCHCH3 CH3 CH3 B) CH3CHOCH3 CH3 CH C) CH3CCH2 CH3 D) CH3 CH3CHCH2 E) CH3 CH3CCHCH2CH3 CH3 7. Which alcohol would initially produce the most stable carbocation when treated with concentrated H2SO4? A) CH3 CH3CCH2 CH3 он CH3 B) CH3CHCHCH3 он CH3 C) CH3CHCH2CH2OH CH3 D) HOCH2 CHCH2CH3 E) CH2 OH CH3CHCH2CH3 Page 4
11. . Which of the following Fischer projections represent a pair of enantiomers? CHE CH2CH3 CH2 -HH-FCC-HB- H HCB-HB- CH2CH3 CH₂CH3 CH₂ HC1h a I and II d. II and III bil and y e. Ивие c I and IV
4. Which of the following carbocations would be likely to undergo rearrangement? A) CH3-CH-CH-CH3 CH3 CH3 B) CH3-CH-?_CH3 CH3 CH3 C) CH3-C-CH2-CH3 D) More than one of the above E) All of the above t he dehydrated to an al
21. Consider the following: CHj CH2 CH-CHCH2 CH CH CH2 CH2 CH2 CH-CH2 CH3 CH-CHCH2 CH2 CH3 CH2-CHCH2 CH2 CH2 CH3 IV which two structures represent the same compound? a. I and II b. II and III c. I and III d. II and IV e. None of these 22. In which of these cases, does the central atom have a zero forma.l charge? a. HEH CH3 OCH3 C. F FBF d. H CH3 H CH3 CH CH3 CCH CH3...
Question 41 (2 points) Which of the following carbocations is (are) likely to undergo rearrangement through a methyl shift? H2C CH3 H3C CH3 H3C CH3 III a) both II and III Ob) both I and II Oc) Od) Question 42 (2 points) For the reaction shown, select the expected major organic product. 1. 1 eq HCI 2. 1 eq HBr Br. CI -Br -CI Ha CI Br + enantiomer + enantiomer + enantiomer CI Br + enantiomer IV 11 III...
1) In the reaction of Cl2 with ethane and UV light, which of the following reactions would be a chain termination event(s)? 1) Cl. + CH3-CH3 CH3-CH2-CI+H. II) CI+ CH3-CH3 CH3-H2C + HCI III) Cl. + CH3-H2C: CH3-CH2-CI IV)Cl2 + CH3-H2C CH3-CH2-CI+ CI: V) Cl2 + UV light - CI+CI- A) reaction V B) reactions I and IV C) reactions III and IV D) reactions I and II E) reaction III 2) Given the chlorination of acetone shown below.choose the...
1) In the reaction of Cl2 with ethane and UV light, which of the following reactions would be a chain termination event(s)? 1) CI: + CH3-CH3 - CH3-CH2-CI+H II) CI+ CH3-CH3 CH3-H2C + HCI III) Cl. + CH3-H2C-CH3-CH2-CI IV) Cl2 + CH3-H2C - CH3-CH2-CI+CI- V) Cl2 + UV light -CI+CI: A) reaction V B) reactions I and IV C) reactions III and IV D) reactions I and II E) reaction III 2) Given the chlorination of acetone shown below, choose...
( 4 ) Arrange the following carbocations in the order of increasing stability (least stable first). СНа OC-CHE H-C-H N - a) IV, I, III, II b) III, I, IV, !! c) III, IV, II, 1 d) I, II, II, I
What is the major product of the following reaction? CH -CH₂-C- CH2-C-CH3 + KOH Br alcohol heat ? сні -CH2-C-CH OH IV. I CH3 -CH-CACH OHH CHE -CH=C-CH3 сн -CH2-C=CH2 II. V. CH3 -CH2-CH-CH2OH TIL A) B) 11 OC) IV D) v