Question

[Refer to the figure for the titration of malonic acid]

a) In the diagram above, indicate clearly the regions where the solution is a buffer.

b) What is the approximate value of pKa1 of malonic acid? (indicate on the diagram).

c) Is it feasible to quantitatively titrate both of the malonic acid endpoints separately? (Yes, No)

d) Give an approximate value of the ideal pKa of an indicator dye for determining the endpoints of the titration shown above.

PH 5 10 15 20 25 30 35 volume of strong base (ml)

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Answer #1

Sol → Equivalent Point pH 7 K Buffer regions 5 10 15 20 25 30 35 Volume I equivalent point where 1 pH = pka malonic acid [pH

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