Copper(I) complexes tend to be tetrahedral rather than octahedral or square planar. Why is this the...
Copper(I) complexes tend to be tetrahedral rather than octahedral or square planar. Why is this the case? Explain your reasoning.
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Copper(I) complexes tend to be tetrahedral rather than
octahedral or square planar. Why is this the...
5) (20 Pts) a) Ni(II) tends to form a variety of complexes w square-planar geometries, while Pd(I...
show cft diagram
5) (20 Pts) a) Ni(II) tends to form a variety of complexes w square-planar geometries, while Pd(IID) and PtII) form predominately square-planar complexes, explain using crystal field theory. b) Another striking difference between these three metals is that the NiIV) oxidation state is very rare, while Pd(IV) is more common and Pt(IV) is very common, explain. Show the CFT diagrams for full credit. ith octahedral, tetrahedral and
5) (20 Pts) a) Ni(II) tends to form a variety...
What is the correct molecular geometry for ICl4-? octahedral, square planar tetrahedral trigonal pyramidal linear trigonal...
What is the correct molecular geometry for ICl4-? octahedral, square planar tetrahedral trigonal pyramidal linear trigonal planar
Which of the following magnetic/geometric descriptions is most likely for [ZnC14]?-ion? O paramagnetic/square planar diamagnetic/octahedral diamagnetic/tetrahedral...
Which of the following magnetic/geometric descriptions is most likely for [ZnC14]?-ion? O paramagnetic/square planar diamagnetic/octahedral diamagnetic/tetrahedral diamagnetic/square planar paramagnetic/tetrahedral
Draw structures for the following square planar and octahedral complexes and identify, using appropriate schematics, whether...
Draw structures for the following square planar and octahedral complexes and identify, using appropriate schematics, whether coordination or optical isomerism can exist for each complex: [PdCl2(NH3)2] [Pt(NH3)4]2+ [Ru(2,2´-bipyridine)3]2+ [CoCl3(NH3)3]
Draw structures for the following square planar and octahedral complexes and identify, using appropriate schematics, whether...
Draw structures for the following square planar and octahedral complexes and identify, using appropriate schematics, whether coordination or optical isomerism can exist for each complex: [PdCl2(NH3)2] [Pt(NH3)4]2+ [Ru(2,2´-bipyridine)3]2+ [CoCl3(NH3)3]
4.) Square planar metal complexes (MLA) are an extreme case of tetragonal elongation, where the metal-ligands...
4.) Square planar metal complexes (MLA) are an extreme case of tetragonal elongation, where the metal-ligands bonds along the z axis of an octahedral complex are stretched until the ligands are completely removed from the metal complex. Using the octahedral crystal field below as a starting point, show how the orbital splitting changes upon elongation of the M-L bonds along the z-axis until the two axial ligands are removed. Label all orbitals and use dashed guidelines to show how individual...
The transition metal ion, Fe(III), can form octahedral or tetrahedral complexes depending on the ligand it...
The transition metal ion, Fe(III), can form octahedral or tetrahedral complexes depending on the ligand it binds to. (a) (i) [Fe(CN)6]3- is a strong field octahedral complex of Fe(III). Draw a labelled orbital energy level diagram that shows both the splitting of the d-orbitals and their electron occupancy in [Fe(CN)6]. (3 marks) (ii) Fe(III) can also form tetrahedral complexes, most of which are weak field. Draw a labelled orbital energy level diagram that shows both the splitting of the d-orbitals...
4.) Square planar metal complexes (ML) are an extreme case of tetragonal elongation, where the metal-ligands...
4.) Square planar metal complexes (ML) are an extreme case of tetragonal elongation, where the metal-ligands bonds along the z axis of an octahedral complex are stretched until the ligands are completely removed from the metal complex. Using the octahedral crystal field below as a starting point, show how the orbital splitting changes upon elongation of the M-L bonds along the z-axis until the two axial ligands are removed. Label all orbitals and use dashed guidelines to show how individual...
electrical conductivity e (B) trigonal bipyramidal (C) octahedral (D) square planar (E) either tetrahedral or square...
electrical conductivity
e (B) trigonal bipyramidal (C) octahedral (D) square planar (E) either tetrahedral or square planar 13) Which aqueous solution has the highest electrical conductivity? (A) 04 M CH3COOH (B) 0.1 M CHCICOOH (C) 0.1 M CHCI2COOH (D) 0.01 M CH3COOH (E) 0.01 M CHCI-COOH, 14) Which pair of the following aqueous solution can produce precipitates? (A) NaNO3 and H.So, 10 d H-C-Cro COOKIES for (a) Teflon and (b) polystyrene (14 EC=( 7 3) Write down a mechanism for...
Crystal Field Question. I understand that octahedral shapes have larger splitting energies then in tetrahedral complexes....
Crystal Field Question.
I understand that octahedral shapes have larger splitting energies
then in tetrahedral complexes. And it would take more energy to
split more electrons. So would the order be from Highest to Lowest:
B>A>C where A, B, C are the compounds listed in their
respective orders.
Between Ni(H20)s2+ ; Ni(en)32+; and lowest and why? Cu(CN)42- which has highest splitting and which has
show cft diagram
5) (20 Pts) a) Ni(II) tends to form a variety of complexes w square-planar geometries, while Pd(IID) and PtII) form predominately square-planar complexes, explain using crystal field theory. b) Another striking difference between these three metals is that the NiIV) oxidation state is very rare, while Pd(IV) is more common and Pt(IV) is very common, explain. Show the CFT diagrams for full credit. ith octahedral, tetrahedral and
5) (20 Pts) a) Ni(II) tends to form a variety...
Which of the following magnetic/geometric descriptions is most likely for [ZnC14]?-ion? O paramagnetic/square planar diamagnetic/octahedral diamagnetic/tetrahedral diamagnetic/square planar paramagnetic/tetrahedral
4.) Square planar metal complexes (MLA) are an extreme case of tetragonal elongation, where the metal-ligands bonds along the z axis of an octahedral complex are stretched until the ligands are completely removed from the metal complex. Using the octahedral crystal field below as a starting point, show how the orbital splitting changes upon elongation of the M-L bonds along the z-axis until the two axial ligands are removed. Label all orbitals and use dashed guidelines to show how individual...
The transition metal ion, Fe(III), can form octahedral or tetrahedral complexes depending on the ligand it binds to. (a) (i) [Fe(CN)6]3- is a strong field octahedral complex of Fe(III). Draw a labelled orbital energy level diagram that shows both the splitting of the d-orbitals and their electron occupancy in [Fe(CN)6]. (3 marks) (ii) Fe(III) can also form tetrahedral complexes, most of which are weak field. Draw a labelled orbital energy level diagram that shows both the splitting of the d-orbitals...
4.) Square planar metal complexes (ML) are an extreme case of tetragonal elongation, where the metal-ligands bonds along the z axis of an octahedral complex are stretched until the ligands are completely removed from the metal complex. Using the octahedral crystal field below as a starting point, show how the orbital splitting changes upon elongation of the M-L bonds along the z-axis until the two axial ligands are removed. Label all orbitals and use dashed guidelines to show how individual...
electrical conductivity
e (B) trigonal bipyramidal (C) octahedral (D) square planar (E) either tetrahedral or square planar 13) Which aqueous solution has the highest electrical conductivity? (A) 04 M CH3COOH (B) 0.1 M CHCICOOH (C) 0.1 M CHCI2COOH (D) 0.01 M CH3COOH (E) 0.01 M CHCI-COOH, 14) Which pair of the following aqueous solution can produce precipitates? (A) NaNO3 and H.So, 10 d H-C-Cro COOKIES for (a) Teflon and (b) polystyrene (14 EC=( 7 3) Write down a mechanism for...
Crystal Field Question.
I understand that octahedral shapes have larger splitting energies
then in tetrahedral complexes. And it would take more energy to
split more electrons. So would the order be from Highest to Lowest:
B>A>C where A, B, C are the compounds listed in their
respective orders.
Between Ni(H20)s2+ ; Ni(en)32+; and lowest and why? Cu(CN)42- which has highest splitting and which has
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