Which of the two routes would generate ethyl-t-butyl ether as the major product and why? Route...
Which of the two routes would generate ethyl-t-butyl ether as the major product (for a Sn2 reaction only) and why? Route A OHTE (The nucleophile generated here is OR ethyl t-butyl ether Route B - OH + (The nucleophile generated here is
14. Which of the following reagents should be used to prepare tert-butyl ethyl ether a) tert-butyl bromide and sodium ethoxide b) tert-butyl alcohol and ethyl bromide c) tert-butyl alcohol and ethanol d) potassium tert-butoxide and ethyl bromide 15. What is the major organic product obtained from the following reaction? A) 1 B) 2 C) 3 D) 4 16. What product is formed when methyloxirane is treated with ethylmannesium bromide followed by treatment with aqueous acid? A) 1-pentanol B) 2-pentanol C)...
28) The reaction of tert-butyl bromide, (CH,)CBr, with ethanol affords the substitution product tert-butyl ethyl ether, (CH)1COCH CH, in acidic conditions. What would happen to the rate of the reaction if the concentration of ethanol was doubled? A) The rate remains the same. B) The rate decreases by a factor of 2 C) The rate increases by a factor of 2. D) The rate increases by a factor of 4. Circle the following alkyl halide that will undergo the fastest...
5. if you wish to synthesize cyclohexyl ethyl ether what would be the best approach? 6. The product of the following reaction would be? 5. If you wish to synthesis cyclohexyl ethyl ether what would be the best approach? (6 points) CH₃ H2 a. Use bromoethane and sodium cylohexylalkoxide b. Use sodium ethoxide and bromocyclohexane c. Ether approach will work equally well. 6. The product of the following reaction would be? (5 points) HEC CH2 0 12 + HC-C-cMgBr он...
A. Explain why an Sn2 reaction between ethyl methyl ether and sodium iodide is not favored but an sn2 reaction between diethyl ether and hydrogen iodide is more favorable. B. Explain why the major product of either reaction is not ethene, even with heating
The boiling points of t-butyl methyl ether (2-methoxy-2-methylpropane) and n-butyl methyl ether (1-methoxybutane) differ by 16 degrees (71 and 55 °C), even though they have the same molecular weight. Draw the two structures below: The boiling points of t-butyl methyl ether (2-methoxy-2-methylpropane) and n-butyl methyl ether (1- methoxybutane) differ by 16 degrees (71 and 55 °C), even though they have the same molecular weight. Draw the two structures below: Which compound has the higher boiling point and why? 1-methoxybutane has...
Show the alkyl bromide and alcohol used to make methyl t-butyl ether using the Williamson ether synthesis to the right of the retrosynthetic arrow. Mapoob a) Show the alkyl bromide and alcohol used to make methyl t-butyl ether using the Williamson ether synthesis to the right of the retrosynthetic arrow. alcohol alkyl bromide click to edit CHa H3 H3 b) Complete the general mechanism by adding curved arrows and drawing the final organic product. (Note that R is an abbreviation...
9. Show two pathways to synthesize cyclopentyl ethyl ether using the Williamson ether synthesis. Which one is preferred and why? (4 pts)
Two routes are under consideration for new highway. The northerly route X would be located about 5 miles from the central business district and would require longer travel distance by local commuter traffic. The southerly route Y would pass directly trough the downtown area and, although its construction cost would be higher, it would reduce the travel time and distance for local commuter. Assume the cost for two route are as follow : Route X Route Y Initial cost Maintenance...
9. Which is the major product of the reaction of methyl Grignard (CH3MgBr) and propiophenone (ethyl phenyl ketone)? CH2CH3 CCH3 CH2CH3 -СCH-CH b) ay ОН OH CH3 CH -ССH-CH, -СCH d) он ОН tor leact first) (hint: add the lone pai