Question

Consider the following gas phase reaction: Cl(g)+F(g)-2CIF(g) If 6.08 liters of Cly(g) gas at 110°C and 0.532 atm is used, wh
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Answer #1

1st calculate mol of Cl2

Given:

P = 0.532 atm

V = 6.08 L

T = 110.0 oC

= (110.0+273) K

= 383 K

find number of moles using:

P * V = n*R*T

0.532 atm * 6.08 L = n * 0.08206 atm.L/mol.K * 383 K

n = 0.1029 mol

From reaction,

Mol of ClF formed = 2*mol of Cl2 reacted

= 2*0.1029 mol

= 0.2058 mol

Given:

P = 0.847 atm

n = 0.2058 mol

T = 165.0 oC

= (165.0+273) K

= 438 K

use:

P * V = n*R*T

0.847 atm * V = 0.2058 mol* 0.08206 atm.L/mol.K * 438 K

V = 8.7331 L

Answer: 8.73 L

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