8. (4 points each) Complete the following two NO2 -ΝΗNH2 O2N- H Teduchion 1) LIAIH (excess)...
8. (4 points each) Complete the following two NO2 -NHNH2 + V ON- reduction 1) LIAIH, (excess) 2) H30*
8. (4 points each) Complete the following two -NHNHA - 02 reduction 1) LIAIH, (excess) 2) H30*
23Dime PROTON 8. (4 points each) Complete the following two reactions, No2 reduction 1) LIATH, (excess) 2) H,09 (Major Organic Product) 9. (5 points) Complete the following reaction. Compare the stability of the organic starting material with the major organic product. Discuss the driving force(s) of this reaction. me ph howet v ph" 1. NaOH, HO NH2 2.HCI, H20 PN h
VII(15pts) The following nitrocubane structure, CH,O16, was thought to be a possible explosive: ON. NO2 O2N NO2 O2N NO2 NO2 O2N :> 8 C(s) +8 O:(g) +4 N,(g) C,N,O(s) A possible decomposition reaction is What is the total volume of gases collected at 1.6 atm and 28.0°C from 2.75 x 102 g of nitrocubane. Also, calculate the partial pressure of cach gas under these conditions.
2) Draw the missing product(s) for each reaction: 2) H3O+ 1) NaBHA 2) H30* 1) LİAİH 2) H30+ 2) H30 1) CH2MgBr (excess) Page 1/3
16) Provide a synthesis for the following transformation. (8 points) O2N
8. Write the product of the following reactions: [2x6=12] Br (1) NaNz (2) LiAIH (3) H2O* obvioblastod Br (1) NaCN (2) LiAIHA (3) H30 (b) NaNO2, HCI - I (c) H NH₂ (d) co, CHANH + CH3NH2 + bi- o-Nitroaniline 1. NaNO2, HCI, H2O 2. CuCN
5. Please predict the products from the following reaction sequence (10 points): 1. LiAIH 4 2. H 3. TsCl, pyridine CHO CHO
Extra Credit II 1) Provide structures for A-J in the following roadmap. H NaN, CHANH, LiAIH soa. B D CH,OH (xs) CH, OH E+ А H, A CHO, 1) KOH, H20 2) H30* NH, SOC, 2) Propose a mechanism for the following transformation, including arrows to describe electron flow, and all intermediates. NaOH
D Question 2 4 pts The reaction of phenol with excess concentrated nitric acid and catalytic sulfuric acid would definitely NOT give which productís)? One or more answers are correct and you will lose points for incorrect answers. OH 02N NO2 NO2 O2N NO2 NO2 NO2 囗E