3. Determine the structures of compounds A through F. SOC NaCO. A- HSOHO 1) LA OH...
11.60 Determine the structures of compounds E through I in the following reaction scheme: 1. NaNH CH OH H.O Br NaOH I H TIOH, CF,CH,OH NaOH Br
11.60 Determine the structures of compounds E through I in the following reaction scheme: 1. NaNH CH OH H.O Br NaOH I H TIOH, CF,CH,OH NaOH Br
1) Provide structures for A-J in the following roadmap. H NaN CH,NH LAIRL CH,OH (XS) CH,OH SOCI, E A B D Fr, Cafe 1) KOH, HO 2) H0 NH, SOCI: 2) Propose a mechanism for the following transformation, including arrows to describe electron flow, and all intermediates. NaOH HO OH
(10 pts total) Give the structures for compounds/reagents A through K in the following road- map. 6-methylhept-1-yne D. SOC F E (1) CH3MgBr in ether (2) H,о* (CH)2CuLi G (1) B (CH3),CH(CH2)3MgBr Na2Cr2O7 С H2SO4 (2) H2O* KCN HCN (1) K (2) H30* (1) J (2) H20* н OH Но OH ERK
1. Determine the structures of the major compounds A through D formed in the following reaction scheme. No mechanisms necessary; only final products. PBr3 NaOH Br 1. BH 2. H2OJOH 2. NaBH4 B: D:
Extra Credit II 1) Provide structures for A-J in the following roadmap. H NaN, CHANH, LiAIH soa. B D CH,OH (xs) CH, OH E+ А H, A CHO, 1) KOH, H20 2) H30* NH, SOC, 2) Propose a mechanism for the following transformation, including arrows to describe electron flow, and all intermediates. NaOH
Determine the structures of compounds K-Y in the following reaction sequences. NH MgBr Ho 1. LIAIH4, ether 2. HO 1. NaOH → M- Mchu >N 2. CH CH Br 2. CH,OH ola.ompelen 1. LIAIH., ether PBrs > p 1. PICH) » Q" 2. Bu- H R 2. H2O NaCN OH PBrya 1 V 1. LIAIH, ether 2. 0 .CHMgBrother 2. CH,OH Challe CHET (excess) NaOH, a HGG OCH CHO X- NaOCH,CHY CH.CH OH 2. NHCI
draw the structures of the following compunds:
1. Draw the structures of the following compounds: a. 3-ethyl-4-methyl-2-hexane 12V DAUI orgian antivollotor b.2-chloro-butyl acetate HDHO c. Ethylbenzene HOHO d. 2-methyl-3-pentanol HD HO-HD-HO-HO HD e. 2-methylpropyl methyl ether
Predict the structures of compounds (0) through (VI) and write the curved arrow mechanisms to justify their formation from their precursors. Write each mechanism on a separate sheet of paper. DUE on D2L on: November 7 SOC pont Show Mg1.CO2, CH,OH (excess) conc. H2SO4 (catalytic) III heat anhydrous 2. H2O (ether Show now tracks 1. CHgMgBr (2 eq.) i anhydrous ether 2. H, 1. LiAIH, in anhydrous ether 2. H3O CH3OH (excess) conc. H, SO, (catalytic) PCC in dichloromethane IV...
21.69 Draw structures for compounds E through H. 1. NaOH, H2O 1. NaOEt, EtOH (a) Diethyl malonate 2. (Bromomethyl)benzene Same as above 1. NaOH, H2O 1. NaOC(CH3)3, (CH3)3COH (b) E 2. 1-lodopentane
1) Circle all of the following compounds that is (are) primary alcohols он HO OH 2) Write the IUPAC of the following compound Но, 3) Write the common name of the following compound Vo 4) Circle the following compounds that has the highest boiling point + oH OH HOMOH 5) Circle which of the following would be a reasonable synthesis of 1-butanol но- H2O 1. BH/THE 2. H2O2. HO H2O H2O 1. BH/THF 2. H2O2, HO