Homework Answers
NaNH2 base and removes the proton and forms the
acetylide ion and then it undergoes the SN2 reaction with alkyl
halide and with carbonyl compounds form the addition product as
follows
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4. Design a way to synthesize the products given below from the given substrates (i.e., Give...
1) Give the products or reagents for the reaction pathways below. 2) Give the methods and reagents to synthesize will need to use a protecting group.) the given product.(You Homework week 1...
1) Give the products or reagents for the reaction pathways below. 2) Give the methods and reagents to synthesize will need to use a protecting group.) the given product.(You Homework week 12H Name Group 1) Give the products or reagents for the reaction pathways below NH2CHs Na CHyO 2) Give the methods and reagents to synthesize the given product. (You will need to use a protecting group.) CH, но
1) Give the products or reagents for the reaction pathways below....
Give the organic products of the reactions below, including the correct regiochemistry and stereochemistry when appropriate....
Give the organic products of the reactions below, including the correct regiochemistry and stereochemistry when appropriate. Write your answers on this sheet. сна HC-C=CH-CH, + HI CH2OOCH3 = CH-CH2CH3 + HBr - Pd + D2 CH H0+ H2O + H2CC =CH-CH2CH3 1) (BH3)2, THE 2) H202, OH CH₃ CH2CO3H H20+ CHE =c.jICH CHCI / KOH H3C + Cl₂
Give the organic products of the reactions below, including the correct regiochemistry and stereochemistry when appropriate....
Give the organic products of the reactions below, including the correct regiochemistry and stereochemistry when appropriate. Write your answers on this sheet. CH3 HCC=CH-CH2 + HI CH,OOCH -C=CH-CH2CH3 + HBr – Pd + D CH3 H20 H2O + HC-C=CH-CH2CH3 1) (BH3)2, THF 2) H,02, OH CH CH,CO2H H30* CH3 CH3 CHCI,/KOH H3C
2) Starting from benzene, use the reagents below to synthesize acetophenone (methyl phenyl ketone). There are...
2) Starting from benzene, use the reagents below to synthesize acetophenone (methyl phenyl ketone). There are two possible ways to accomplish this; give both. You may draw the intermediates in any format. Starting from benzene you have to figure out how to make the appropriate Grignard reagent 2 in two steps... 3) A, B, C, D, E? Route A: Choose one СН3 Na2Cr207 H.S04. H2O H30® workup Now convert Intermediate 2 to acetophenone... 2- acetophenone Route B: Choose one 3)...
how many synthetic connections for alkene and alkyne 2. Is the Zaitsev Rule wrong? Explain the following observation...
how many synthetic connections for alkene and
alkyne
2. Is the Zaitsev Rule wrong? Explain the following observation. Make comparative predictions about the rate constants ki and k2. 80% 20% on CH₂ 100% 3. Using curved arrows to show the movement of electron pairs, give a detailed mechanism for the following reactions. H2SO4 H20 195010 - + H20 H2SO4 H2O CH3 H3C-C-CH2-OH- CHE HECH = + H₂O H₃C CH₂ 4. See how many synthetic connections you can make on the...
(References) Not Submitted Give IUPAC names for the following structures. If appropriate, specify relative stereochemistry. 1st...
(References) Not Submitted Give IUPAC names for the following structures. If appropriate, specify relative stereochemistry. 1st structure: 1,3- 2nd structure: cyclopropoxy Submit Answer Try Another Version 10 item attempts remaining Br + HCECH + H2C-CH, H₂C & ОН Hic . Hoc m -CECH Br HCECH OTBDMS OTBDMS H3C OTBDMS HC OH HEC Shown above is the stepwise synthesis of (7Z, TIE)-7,11-hexadecadien-1-ol, the key intermediate for synthesis of Gossyplure, the sex pheromone of the pink bollworm. From the choices provided below,...
*Ignore the structures drawn in pencil. The purple lines indicate that they are incorrect. 23. As 5 points. Complete 10 of the 15 following reactions by providing the missing information: reac...
*Ignore the structures drawn in pencil. The purple lines
indicate that they are incorrect.
23. As 5 points. Complete 10 of the 15 following reactions by providing the missing information: reactants products or reagents and conditions. When predicting products, you must include all products that will most likely form in an appreciable amount. When more than one product is likely, label the major and minor products. (Watch out for rearrangements). Where appropriate, indicate stereochemistry, as well as whether or not...
PROBLEMS 1. Reagents. Give the structures of the major products (A-G) expected from the following reactions....
PROBLEMS 1. Reagents. Give the structures of the major products (A-G) expected from the following reactions. Assume standard aqueous workup conditions are used for product isolation. a. OH 1. TBSCI imidazole, CH2Cl2 ► DMF, -18°C tot HO OH2. NalO4, CH2Cl2 large excoss A 80% b. олон 1. TSCI. py B "CH, 2. LiEt3BH. THE c. MeOC O H OH 1. TICI (1 cq) py, cat. DMAP - 2. TBSOT 2,6-lutidine, CH2Cl2 C1 79% 3. LIBHA, THE 4. Php. 12 imidazole...
1.) (9 points) Give structures for the following compounds: a) meta-phenylphenol b) 6-benzyl-3-heptanol e) ortho-sec-butyltoluene 2.)...
1.) (9 points) Give structures for the following compounds: a) meta-phenylphenol b) 6-benzyl-3-heptanol e) ortho-sec-butyltoluene 2.) (9 points) Name the following compounds: 3.) (8 points) Label the following molecules as aromatic, anti-aromatic, or non-aromatic. For the ones th aren't aromatic, explain why they are either non-aromatic or anti-aromatic. 0.8 4.) (11 points) For the following electrophilic aromatic substitution reaction: Вт, FeBr; a) Which product is the major one? b) Draw a complete mechanism for the formation of the major product...
CHEM 2343A HOMEWORK W13 Name: DUE 11/18/19 at 9:10 AM There are total of 4 questions...
CHEM 2343A HOMEWORK W13 Name: DUE 11/18/19 at 9:10 AM There are total of 4 questions on this homework assignment 1. For the reaction outlined below in la and I draw out the reaction mechanism using arrow formalism to describe how the reaction below occurs. Be sure to draw out all action intermediates & the moment of all electrons needed to justify the formation of the indicand product. You do not need to add in any reagents that are not...
1) Give the products or reagents for the reaction pathways below. 2) Give the methods and reagents to synthesize will need to use a protecting group.) the given product.(You Homework week 12H Name Group 1) Give the products or reagents for the reaction pathways below NH2CHs Na CHyO 2) Give the methods and reagents to synthesize the given product. (You will need to use a protecting group.) CH, но
1) Give the products or reagents for the reaction pathways below....
Give the organic products of the reactions below, including the correct regiochemistry and stereochemistry when appropriate. Write your answers on this sheet. сна HC-C=CH-CH, + HI CH2OOCH3 = CH-CH2CH3 + HBr - Pd + D2 CH H0+ H2O + H2CC =CH-CH2CH3 1) (BH3)2, THE 2) H202, OH CH₃ CH2CO3H H20+ CHE =c.jICH CHCI / KOH H3C + Cl₂
Give the organic products of the reactions below, including the correct regiochemistry and stereochemistry when appropriate. Write your answers on this sheet. CH3 HCC=CH-CH2 + HI CH,OOCH -C=CH-CH2CH3 + HBr – Pd + D CH3 H20 H2O + HC-C=CH-CH2CH3 1) (BH3)2, THF 2) H,02, OH CH CH,CO2H H30* CH3 CH3 CHCI,/KOH H3C
2) Starting from benzene, use the reagents below to synthesize acetophenone (methyl phenyl ketone). There are two possible ways to accomplish this; give both. You may draw the intermediates in any format. Starting from benzene you have to figure out how to make the appropriate Grignard reagent 2 in two steps... 3) A, B, C, D, E? Route A: Choose one СН3 Na2Cr207 H.S04. H2O H30® workup Now convert Intermediate 2 to acetophenone... 2- acetophenone Route B: Choose one 3)...
how many synthetic connections for alkene and
alkyne
2. Is the Zaitsev Rule wrong? Explain the following observation. Make comparative predictions about the rate constants ki and k2. 80% 20% on CH₂ 100% 3. Using curved arrows to show the movement of electron pairs, give a detailed mechanism for the following reactions. H2SO4 H20 195010 - + H20 H2SO4 H2O CH3 H3C-C-CH2-OH- CHE HECH = + H₂O H₃C CH₂ 4. See how many synthetic connections you can make on the...
(References) Not Submitted Give IUPAC names for the following structures. If appropriate, specify relative stereochemistry. 1st structure: 1,3- 2nd structure: cyclopropoxy Submit Answer Try Another Version 10 item attempts remaining Br + HCECH + H2C-CH, H₂C & ОН Hic . Hoc m -CECH Br HCECH OTBDMS OTBDMS H3C OTBDMS HC OH HEC Shown above is the stepwise synthesis of (7Z, TIE)-7,11-hexadecadien-1-ol, the key intermediate for synthesis of Gossyplure, the sex pheromone of the pink bollworm. From the choices provided below,...
*Ignore the structures drawn in pencil. The purple lines
indicate that they are incorrect.
23. As 5 points. Complete 10 of the 15 following reactions by providing the missing information: reactants products or reagents and conditions. When predicting products, you must include all products that will most likely form in an appreciable amount. When more than one product is likely, label the major and minor products. (Watch out for rearrangements). Where appropriate, indicate stereochemistry, as well as whether or not...
PROBLEMS 1. Reagents. Give the structures of the major products (A-G) expected from the following reactions. Assume standard aqueous workup conditions are used for product isolation. a. OH 1. TBSCI imidazole, CH2Cl2 ► DMF, -18°C tot HO OH2. NalO4, CH2Cl2 large excoss A 80% b. олон 1. TSCI. py B "CH, 2. LiEt3BH. THE c. MeOC O H OH 1. TICI (1 cq) py, cat. DMAP - 2. TBSOT 2,6-lutidine, CH2Cl2 C1 79% 3. LIBHA, THE 4. Php. 12 imidazole...
1.) (9 points) Give structures for the following compounds: a) meta-phenylphenol b) 6-benzyl-3-heptanol e) ortho-sec-butyltoluene 2.) (9 points) Name the following compounds: 3.) (8 points) Label the following molecules as aromatic, anti-aromatic, or non-aromatic. For the ones th aren't aromatic, explain why they are either non-aromatic or anti-aromatic. 0.8 4.) (11 points) For the following electrophilic aromatic substitution reaction: Вт, FeBr; a) Which product is the major one? b) Draw a complete mechanism for the formation of the major product...
CHEM 2343A HOMEWORK W13 Name: DUE 11/18/19 at 9:10 AM There are total of 4 questions on this homework assignment 1. For the reaction outlined below in la and I draw out the reaction mechanism using arrow formalism to describe how the reaction below occurs. Be sure to draw out all action intermediates & the moment of all electrons needed to justify the formation of the indicand product. You do not need to add in any reagents that are not...
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