02 Question (1 point) Label the following free energy diagram with the proper structures of the...
Draw a labelled reaction coordinate diagram for the both SN reactions. Label the activation energy (free energy of activation) and give the approximate structures of the intimal state, the transition states, the intermediate and product at the correct points along the reaction coordinate. Also, can you decide on the basis of the kinetic expression whether the t-butyl chloride-hydroxide ion reaction proceeds by a one-step or a two-step mechanism? Explain why observed kinetic expression is consistent with the mechanism you chose.
using the boxes on the diagram below, fill in the appropriate structures in each of the boxes for an E, reaction, taking into account the approximate energy levels of the potential products. For example, the intermediate should include a structure with a carbocation. Label the transition state(s) with a f. EIOH E1 elimination product (assume no rearrangement) reflux Energy Reaction Coordinate Full mechanism:
Which Newman projection corresponds to point A on the graph of potential energy vs rotation about the C2 Cz bond? Potential Energy s A 0 60 300 360 120 180 240 Degrees of Rotation CH; HI H H H CH; CIL HCH: нен H HH H CH CH H CH CIL 11 11 11 What is the major product of the following reaction? Br NaOMe, MeOH D Δ Ome A B C D 'D D H D B с D...
2014 Reaction Quiz 2 (4 pages) Name: 1. Draw an expected product. 2. Assign R or S to anv stereocenter created in the product you show. A Product Starting Material Reagents or Reaction OsO, Н.с Br Br н.с Br -Br H -OH (NOT the same product as previous above) (water) н,с H, H20 Н,с H, H20 FAssign R or S! MCPBA IDENTICAL
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8. (9 points) Draw the energy diagram for a spontaneous, exothermic reaction. Label the free energy of activations, the free energy of reaction, the transition states, the intermediate and the correct axis. (8 points) Sketch the mechanism of either: a). The polar addition of HBr to ethylene or b). The three steps of a radical reaction between Cl, and CH
H 21. What is the major product of this reaction? H-SO 22. Which energy diagram corresponds to this mechanism? CH +Br ㄑㄧ-t.H. 。 CHy CH3 Reaction coordinate Reaction coordinate → Reaction coordinate → Reaction coordinate →
**WRITTEN WORK** Draw a detailed free energy diagram for the following Snl reaction. Include and label the overall reactants, the overall products, the intermediate(s), the axis, and the transition state(s). Br C1 Syl HTML Editore n = = X Х D
Consider a typical Sgi pathway involving the reaction of 2-bromo-2-methylpropane with hydroxide as shown below. CH HC-C-Br -NaOH Syl CH; A reaction energy diagram for this reaction is provided below. What intermediate from the list below is present at position (2) on this diagram? G (1) (5) Reaction Coordinate CH; CH; CH; НО С-.--В сох с — Br HẠC CH А HẠC CHỦ B HỌC CHỦ с CH, CH; CH; НО- НО. -cs Н;С сн; Н;С сн D HẠC CHỜ...
QUESTION 33 Match each arrow letter with the proper label. B C Potential Energy D A E Reaction Coordinate CH(g) + 2O5(g)-CO-(g) + 2H2O + S90,4kg 1. Potential energy of the reactants Click Save and Submit to save and submit. Click Save an Answers to save all ansers Type here to search O 994 Reaction Coordinate CH,(g) + 20g) - CO2(g) + 2H2O(0) + 890.4 kJ 1. Potential energy of the reactants Arrow A 2. Activation Energy of the forward...
2. Draw an energy diagram for the first reaction in problem #1. Label the axis, reactants, products, any intermediates (if needed) and transition states. Than indicate using dotted a line how the diagram would change if CH,CH2OH was used as the solvent instead of acetone. 3. Draw the mechanism showing how the following molecule can best be produced using a SN2 reaction (the molecule shown below is the product, you need to determine the proper reactants (RX and Nu)).