Answer:-
(a)-
Given:-
molarity of solution (M1) = 0.70 M
volume of solution (V1) = 1.10 L = 1.10 1000 = 1100 mL
molarity of concentrated H2SO4 (M2) = 18 M
volume of concentrated H2SO4 (V2) = ?
According to the formula
M1V1 = M2V2
therefore
molarity of solution (M1) volume of solution (V1) = molarity of concentrated H2SO4 (M2) volume of concentrated H2SO4 (V2)
volume of concentrated H2SO4 (V2) = molarity of solution (M1) volume of solution (V1) / molarity of concentrated H2SO4 (M2)
volume of concentrated H2SO4 (V2) = 0.70 M 1100 mL / 18 M
volume of concentrated H2SO4 (V2) = 770 mL / 18
volume of concentrated H2SO4 (V2) = 42.78 mL
So
volume of water added = volume of solution (V1) - volume of concentrated H2SO4 (V2)
volume of water added = 1100 mL - 42.78 mL
volume of water added = 1057.22 mL
therefore
Dilute 42.78 mL of concentrated H2SO4 with 1057.22 mL of water.
(b)-
Given:-
molarity of solution (M1) = 0.70 M
volume of solution (V1) = 1.10 L = 1.10 1000 = 1100 mL
molarity of concentrated HCl (M2) = 12 M
volume of concentrated HCl (V2) = ?
According to the formula
M1V1 = M2V2
therefore
molarity of solution (M1) volume of solution (V1) = molarity of concentrated HCl (M2) volume of concentrated HCl (V2)
volume of concentrated HCl (V2) = molarity of solution (M1) volume of solution (V1) / molarity of concentrated HCl (M2)
volume of concentrated HCl (V2) = 0.70 M 1100 mL / 12 M
volume of concentrated HCl (V2) = 770 mL / 12
volume of concentrated HCl (V2) = 64.17 mL
So
volume of water added = volume of solution (V1) - volume of concentrated HCl (V2)
volume of water added = 1100 mL - 64.17 mL
volume of water added = 1035.83 mL
therefore
Dilute 64.17 mL of concentrated HCl with 1035.83 mL of water.
(c)-
Given:-
molarity of NiCl2.6H2O solution (M1) = 0.70 M = 0.70 mol / L
volume of NiCl2.6H2O solution (V1) = 1.10 L = 1.10 1000 = 1100 mL
wt.of NiCl2.6H2O = ?
As we know that
molar mass of NiCl2.6H2O = molar mass of Ni + 2 molar mass of Cl + 6 ( 2 molar mass of H + molar mass of O)
molar mass of NiCl2.6H2O = 58.69 + 2 35.5 + 6 ( 2 1 + 16)
molar mass of NiCl2.6H2O = 58.69 + 71.0 + 6 ( 18)
molar mass of NiCl2.6H2O = 58.69 + 71.0 + 108
molar mass of NiCl2.6H2O = 237.69 g/mol
Also we know that
molarity of compound = wt. of compound (g) / molar mass of compound (g/mol) volume of solution (L)
wt. of compound (g) = molarity of compound molar mass of compound (g/mol) volume of solution (L)
therefore
wt. of NiCl2.6H2O = molarity of NiCl2.6H2O solution molar mass of NiCl2.6H2O (g/mol) volume of NiCl2.6H2O solution (L)
wt. of NiCl2.6H2O = 0.70 mol / L 237.69 g/mol 1.10 L
wt. of NiCl2.6H2O = 183.02 g
So
Dissolve 183.02 g of NiCl2.6H2O in water , and add water until the total volume of the 1.10 L or 1100 mL.
(d)-
Given:-
molarity of Na2CO3 solution (M1) = 0.70 M = 0.70 mol / L
volume of Na2CO3 solution (V1) = 1.10 L = 1.10 1000 = 1100 mL
wt.of Na2CO3 = ?
As we know that
molar mass of Na2CO3 = 2 molar mass of Na + molar mass of C + 3 molar mass of O
molar mass of Na2CO3 = 2 23 + 12 + 3 16
molar mass of Na2CO3 = 46 + 12 + 48
molar mass of Na2CO3 = 106 g/mol
Also we know that
molarity of compound = wt. of compound (g) / molar mass of compound (g/mol) volume of solution (L)
wt. of compound (g) = molarity of compound molar mass of compound (g/mol) volume of solution (L)
therefore
wt. of Na2CO3 = molarity of Na2CO3 solution molar mass of Na2CO3 g/mol) volume of Na2CO3 solution (L)
wt. of Na2CO3 = 0.70 mol / L 106 g/mol 1.10 L
wt. of Na2CO3 = 81.62 g
So
Dissolve 81.62 g of Na2CO3 in water , and add water until the total volume of the 1.10 L or 1100 mL.
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