NiCl2·2H2O + 2 PPh3 + 2 HC(OC2H5)3 → [NiCl2(PPh3)2] + 2 HC(O)OC2H5 + 4 C2H5OH
and
NiCl2·2H2O + dppe + 2 HC(OC2H5)3 → [NiCl2(dppe)] + 2 HC(O)OC2H5 + 4 C2H5OH
where Ph = C6H5 and dppe = Ph2PCH2CH2PPh2.
MW of [NiCl2(PPh3)2]= 654.2 g/mol
MW of NiCl2·2H2O= 165.6 g/mol
MW of PPh3= 262.3 g/mol
Mw of Triethyl orthoformate HC(OC2H5)3 = 148.2 g/mol
density of triethyl orthoformate HC(OC2H5)3 = 0.891 g/ mL
NiCl2·2H2O + 2 PPh3 + 2 HC(OC2H5)3 → [NiCl2(PPh3)2] + 2 HC(O)OC2H5 + 4 C2H5OH and...
Consider the overall balanced chemical equation: Ni(NO3)2·6H2O + 2 NaY + 2 PPh3 + 6 HC(OC2H5)3 → [NiY2(PPh3)2] + 2 NaNO3 + 12 C2H5OH + 6 HC(O)OC2H5 where Ph = C6H5 and Y = SCN or NCS (ambidentate ion). MW of Ni(NO3)2·6H2O = 290.8 g/mol MW of NaSCN= 81.07 g/mol MW of PPh3= 262.3 g/mol MW of [NiY2(PPh3)2] (Y = SCN or NCS) = 699.5 g/mol If 0.252 g of Ni(NO3)2 6H20 reacts with 1.77 mmol of NaSCN and 1.65 mmol...
g. Ph-C(O)-NH2 4 NaOH Br2 h. (HC)2CH-C(CHa)2 -> HO N(CH3)3 i. Ph-N2, CI- + CuCN --> H30* (cat) Na/ETOH j. cyclohexanone+ H2NOH Pd(OAc)2 (1 mole%) k. Ph-I + 4-O2N-C&H4-HC=CH2 Cul/Pd(PPH3)4) L. HO-CH2-CH2-CC-H +1-CH=CH-(CH2)4-CH3
heat 4 Fe(s) +3 CO,(g) 2 Fe,0,(6)+3 C(s) Calculate the number of grams of Fe, O, needed to react with 20.0 g C mass of Fe,O,: Phosphorus reacts with oxygen to form diphosphorus pentoxide, P,O, 4 P(s) +50,(g)2P,0,(6) How many grams of P,O, are formed when 3.11 g of phosphorus reacts with excess oxygen? Show the unit analysis used for the calculation by placing the correct components into the unit-factor slots. g P,O X 3.11 g PX Answer Bank I...