The given reaction is
8SO2 + 16H2S 3S8 + 16H2O
Lets calculate the moles of reactants
Molar mass of SO2 = 64.06 g/mol
Molar mass of H2S = 34.08 g/mol
using formula Moles = mass / molar mass
Moles of SO2 = 77.0 g / 64.06 g/mol = 1.2020 mol SO2
Moles of H2S = 77.0 g/ 34.08 g/mol = 2.2594 mol H2S
Now lets see moles of H2S reacts with moles of SO2
then , 2.2594 mol H2S would react completely with 2.2594 mol ( 3 mol S8 / 16 mol H2S ) = 0.42 mol SO2
but as per above calculation there is more SO2 present
So SO2 is in excess and H2S is limiting reactant
So
maximum mass of S8 = 2.2594 mol H2S (3 mol S8 / 16 mol H2S) molar mass of S8
= 2.2594 mol H2S (3 mol S8 / 16 mol H2S) 256.52 g/mol
= 108.67 g S8
So our answer is 108.67 g S8
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