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![Gesce = sius (2-) = () (smug # -si 270)] sinoo Sin 2020 и амч амим n any har En = n24² 8m22 = En kiE 1242 8m22 3 L=1mm = 109m](http://img.homeworklib.com/questions/e1e683c0-717b-11ea-b22f-9f322278de68.png?x-oss-process=image/resize,w_560)
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2. Consider an electron in a 1D potential box (V(x) = 0 for 0<x<L, V(x) =...
8. Consider one electron in a 1D box of side L. Its wavefunction is given by...
8. Consider one electron in a 1D box of side L. Its wavefunction is given by из where ф1(x), фг(x), and фз(x) are the first 3 eigenfunctions of the Hamiltonian, H, of a particle in a 1D box, 2m dx2 a) Is Ψ(x) normalized? If it is not normalized it, normalize it! b) Is Ψ(x) an eigenfunction of A? If it is an eigenfunction, what is the 9. A linear polyene contains 8 -electrons, and absorbs light with412 nm. b)...
Particle with a speed bump Consider our old friend the 1D particle in the box, except...
Particle with a speed bump Consider our old friend the 1D particle in the box, except now with a speed bump in the box so the potential now is given by L and L < x < L 0, Vo 0 x V (x) otherwise (a) Calculate the first order correction to the ground state (n = 1) and first excited state (n = 2) energies (b) Calculate the first order correction to the ground state wave function in terms...
1. Consider a 1D finite square well potential defined as follows. Vo-a<x<a V(x) = 0otherwise a)...
1. Consider a 1D finite square well potential defined as follows. Vo-a<x<a V(x) = 0otherwise a) What are the energy eigenfunctions n of the Hamiltonian for a single particle bound in this potential? You may write your answer in piece-wise form, with an arbitrary normalization. b) Derive the characteristic equation that the energy eigenvalues E, must satisfy in order to satisfy the eigenvalue equation Hy,-EnUn for eigen function Un c) Write a computer program1 to find the eigenvalues E, for...
II.6. The wave function of a particle in a 1D rigid box (infinite potential well) of...
II.6. The wave function of a particle in a 1D rigid box (infinite potential well) of length L is: v, 8, 1) = sin(x)e-En/5). n = 1,2,3... What is the probability density of finding the particle in its 2nd excited state?
Q4. Consider the 1D infinite square-well potential shown in the figure below. V(x) O0 Position (a)...
Q4. Consider the 1D infinite square-well potential shown in the figure below. V(x) O0 Position (a) State the time-independent Schrödinger equation within the region 0<x<L for a particle with positive energy E 2 marks] (b) The wavefunction for 0<x< L can be written in the general form y(x) = Asin kx + B cos kx. Show that the normalised wavefunction for the 1D infinite potential well becomes 2sn'n? ?snT/where ( "1,2,3 ! where ( n = 1,2,5, ). [4 marks]...
8. Consider one electron in a 1D box of side L. Its wavefunction is given by...
8. Consider one electron in a 1D box of side L. Its wavefunction is given by V3 V3 2V3i where ф1(x), фг(x), and фз(x) are the first 3 eigenfunctions of the Hamiltonian, A, of a particle in a 1D box, h2 d2 a) Is Ψ(x) normalized? If it is not normalized it, normalize it! b) Is ų (x) an eigenfunction of A? If it is an eigenfunction, what is the eigenvalue?
(III) Quantum Tunneling Consider an electron in 1D in presence of a potential barrier of width...
(III) Quantum Tunneling Consider an electron in 1D in presence of a potential barrier of width L represented by a step function ſo I<0 or 1>L V U. r>0 and 2<L The total wavefunction is subject to the time-independent Schrödinger equation = EV (2) 2m ar2 +V where E is the energy of the quantum particle in question and m is the mass of the quantum particle. A The total wavefunction of a free particle that enters the barrier from...
1. (50 points) Consider the particle in a one-dimensional box (0 s x S L). Assume a term is added to the Hamiltonian of the form: πχ V(x)g sin Sketch the potential and the expected eigenfunction (...
1. (50 points) Consider the particle in a one-dimensional box (0 s x S L). Assume a term is added to the Hamiltonian of the form: πχ V(x)g sin Sketch the potential and the expected eigenfunction (small g). In the limit of small g, find the second order correction to the ground state energy 2. (50 points) For a diatomic molecule rotating in free space, the Hamiltonian may be written: 12 21 Where L is the total angular momentum operator,...
We have potential of 0, 0 < x < a. V(x) = Joo, elsewhere. a Find...
We have potential of 0, 0 < x < a. V(x) = Joo, elsewhere. a Find the ground state energy and the first and second excited states, if an electron is enclosed in this potential of size a = 0.100 nm. b Find the ground state energy and the first and second excited states, if a 1 g metal sphere is enclosed in this potential of size a = 10.0 cm. c Are the quantum effects important for both systems?...
6. a) Calculate the expectation value of x as a function of time for an electron...
6. a) Calculate the expectation value of x as a function of time for an electron in a state that is a (normalized) equal mixture of the ground state and 1st excited state of a 1D HO b) Graph x vs time for the case k = 1 eV/nm2. What is its value at t=0? What is the period of the oscillation in femtoseconds? For the one-dimensional (1D) harmonic oscillator (HO) the potential energy function has the form V(a) k2/2,...
8. Consider one electron in a 1D box of side L. Its wavefunction is given by из where ф1(x), фг(x), and фз(x) are the first 3 eigenfunctions of the Hamiltonian, H, of a particle in a 1D box, 2m dx2 a) Is Ψ(x) normalized? If it is not normalized it, normalize it! b) Is Ψ(x) an eigenfunction of A? If it is an eigenfunction, what is the 9. A linear polyene contains 8 -electrons, and absorbs light with412 nm. b)...
Particle with a speed bump Consider our old friend the 1D particle in the box, except now with a speed bump in the box so the potential now is given by L and L < x < L 0, Vo 0 x V (x) otherwise (a) Calculate the first order correction to the ground state (n = 1) and first excited state (n = 2) energies (b) Calculate the first order correction to the ground state wave function in terms...
1. Consider a 1D finite square well potential defined as follows. Vo-a<x<a V(x) = 0otherwise a) What are the energy eigenfunctions n of the Hamiltonian for a single particle bound in this potential? You may write your answer in piece-wise form, with an arbitrary normalization. b) Derive the characteristic equation that the energy eigenvalues E, must satisfy in order to satisfy the eigenvalue equation Hy,-EnUn for eigen function Un c) Write a computer program1 to find the eigenvalues E, for...
II.6. The wave function of a particle in a 1D rigid box (infinite potential well) of length L is: v, 8, 1) = sin(x)e-En/5). n = 1,2,3... What is the probability density of finding the particle in its 2nd excited state?
Q4. Consider the 1D infinite square-well potential shown in the figure below. V(x) O0 Position (a) State the time-independent Schrödinger equation within the region 0<x<L for a particle with positive energy E 2 marks] (b) The wavefunction for 0<x< L can be written in the general form y(x) = Asin kx + B cos kx. Show that the normalised wavefunction for the 1D infinite potential well becomes 2sn'n? ?snT/where ( "1,2,3 ! where ( n = 1,2,5, ). [4 marks]...
8. Consider one electron in a 1D box of side L. Its wavefunction is given by V3 V3 2V3i where ф1(x), фг(x), and фз(x) are the first 3 eigenfunctions of the Hamiltonian, A, of a particle in a 1D box, h2 d2 a) Is Ψ(x) normalized? If it is not normalized it, normalize it! b) Is ų (x) an eigenfunction of A? If it is an eigenfunction, what is the eigenvalue?
(III) Quantum Tunneling Consider an electron in 1D in presence of a potential barrier of width L represented by a step function ſo I<0 or 1>L V U. r>0 and 2<L The total wavefunction is subject to the time-independent Schrödinger equation = EV (2) 2m ar2 +V where E is the energy of the quantum particle in question and m is the mass of the quantum particle. A The total wavefunction of a free particle that enters the barrier from...
1. (50 points) Consider the particle in a one-dimensional box (0 s x S L). Assume a term is added to the Hamiltonian of the form: πχ V(x)g sin Sketch the potential and the expected eigenfunction (small g). In the limit of small g, find the second order correction to the ground state energy 2. (50 points) For a diatomic molecule rotating in free space, the Hamiltonian may be written: 12 21 Where L is the total angular momentum operator,...
We have potential of 0, 0 < x < a. V(x) = Joo, elsewhere. a Find the ground state energy and the first and second excited states, if an electron is enclosed in this potential of size a = 0.100 nm. b Find the ground state energy and the first and second excited states, if a 1 g metal sphere is enclosed in this potential of size a = 10.0 cm. c Are the quantum effects important for both systems?...
6. a) Calculate the expectation value of x as a function of time for an electron in a state that is a (normalized) equal mixture of the ground state and 1st excited state of a 1D HO b) Graph x vs time for the case k = 1 eV/nm2. What is its value at t=0? What is the period of the oscillation in femtoseconds? For the one-dimensional (1D) harmonic oscillator (HO) the potential energy function has the form V(a) k2/2,...
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