Show all possible reactions 1. Oxidative cleavage of an alkene(either using KMnO./OH-/H,O or O/CH,Clat-78*C in DMSO)
Show all possible reactions (Label reagents, products, reactants, and mechanisms) 1. Oxidative cleavage of an alkene(either using KMnO./OH-/H.O or O/CH.Chat-78*C in DMSO)
2. Predict the product(s) using the same alkene reactant for the following reactions: H,O, hv H5OH,O 1, HE. THI -H0 2. NaBH,/NaOH 1. B H/THF 2. H.O./NaOH KMnO /H,0 cold 1. Oso 2. NaHSO 1. KMnO/OH heat 2. H,0 1. O,/CH,CI, 2. Zn/H,0 1.0, 2. H,O/OH
18 41 OsONaHSO) or KMnO/OH A H alkene + ОН Draw the structure of the alkene There are two answers. Give both. 42. ОН ОН CH CH3 Н The bond between the bold-face Cs is the weakest in this molecule. Explain why in terms of partial charges. CP-CH CP iod w CH) H* KMnO4 CH2-C-C C- CHs ОН Give the three organic products of this reaction. E 1 1 1 OICIH
Predict the product(s) using the same alkene reactant for the following reactions: 2. н, (a) Pt/C D, (b) Pt/C Cl, (c) CH,Cl, Br, (d) Н.о Cl, (e) CH,OH HI (0 DBr (g) НВr (h) нолу ноно (0) 1. Hg". THF-H,O 2. NaBH/NaOH 1. В, Н, ТHF (k) 2. H,O/NaOH кMпо, H,о (I) cold 1. OsO, (m) 2. NaHSO, 1. KMnO/OH/heat (n) 2. Н.О" 1. 0/CH,CI, (o) 2. Zn/H,O 1. O, (p) 2. H.о/он
3. Predict the product(s) using the same alkene reactant for the following reactions: HB H.O, hv H.0/H,0 1, HE, THI | 0 2. NaBH,/NaOH 1. B.H/THF 2. H.O./NaOH KMnO,H,O cold 1. Oso 2. NaHSO, 1. KMnO,/OH/heat 2. H,0 1. O,CH,CI 2. Zn/H,
Hi I need help predicting the products for these reactions OEt NaOCH.CH CH,CH OH b. H, O/H,0 a. NaOCH.CH CH,CH,OH b. Br c. NaOHH O, beat d. H2O*/H2O 1. NaCN, DMSO 2. CH,MgBr, Eto 3. H.O/H,O EN 2. NaH, CH,Br chemoselective 1. a. NaOet, EtOH Br b. 2. a. NaOH/H,O, heat b. H30+/H20 CY.NECEN cy OH b. then add HC-NH2 a. NaCN, DMSO b. HO*/H,0
15.35 Complete the following reactions: O С — ОН H+, heat +CH,CH - OH CH, C-Cl +CH,CH-OH - DEL CH, simulado O soldatto -C -0 -C. +CH, - OH - 1
146 ChemActivity 10: Oxidation and Reduction Model 8: Stereoselective Oxidative Cleavage of a x Bond Synthetic Transformation 10.9: Syn Addition of Two OH Groups to ax Bond H OH но OsO4 or OH NaHSO a cold, dilute KMnO, solution, followed by KOH can be used in place of the highly toxic OsO Review of Synthetic Transformations 9.3/9.4 H HOHO OH acide ring opening eр МCРВА or 1) Кон. 2) neutrize with dilute acid basic ring opening он Critical Thinking Question...
Hot KMnO, OH H,01 ? 1. CHECO,H 2. H2O /H,O* Cold KMnO4 H2O/OH dah MCPBA , CH, MCPBA CH3CH2CH2CH2C= Na/CH3CH2NH2 CCH2CH3 Hydrogenation
Show the Sul mechanism and producto for the following reactions: o CH₂-c-c-c-CH₂ çhz Bra _H2O OH Crizh chis H₂O to chache Loty Br 6 CH3 Ý to CH₂CH=C - C- CH₂ H2O HO Br