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This reaction is ion exchange reaction. while dissolving the potassium acetate in to water it dissociates into potassium +1 ion and acetate -1 ion while HBr follows the same and dissociates into H+ and Br- they exchange their ions with each other and form KBr and CH3COOH.

CH3COO-K+ + H+Br-  \rightarrow CH3COOH + KBr

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