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How would you convert C into D? Give a reaction mechanism for the production of E...
just yellow question < Back Homework Chapter 16 16.33 Show how you would convert benzaldehyde into...
just yellow question
< Back Homework Chapter 16 16.33 Show how you would convert benzaldehyde into cach of the following. You may use any other needed reagents, and more than one step may be required. (a) Benzyl alcohol (F) 3-Methyl-1-phenyl-1-butanol (k) CHCHDOH (b) Benzoic acid (g) Benzyl bromide (1) CH.CH(OH)CN (c) Benzoyl chloride (h) Toluene (m) CHECHNOH (d) Benzophenone (i) CH CH(OCH (n) CHECHNNHCHE (e) 1-Phenylethanol G) CH.CH (o) C.H.CHCHCHCH, 16.36 Give structures for compounds A-E. Cyclohexanol in A (CHO)...
Problem 16.33 Show how you would convert benzaldehyde into each of the compounds using the reagents...
Problem 16.33 Show how you would convert benzaldehyde into each of the compounds using the reagents (A - G) in the table below where necessary. H20+ PBrz NaBH4 A: (1) AICI: (2) H307 SOCI2 Ag(NH3)2 NHz/H20 B: C: D: LiAIH4 E: F: G: X Incorrect. (c) C6H5CHENNHC6H5 + CH stereoisomer (E)-1-phenyl-2-(phenylmethylidene)hydrazine A: PPhz Edit H3C X Incorrect. (d) CGHSCH=CHCH=CH2 H B (a Wittig reagent) B: ? Edit Problem 16.49 Compounds W and X are isomers; they have the molecular formula...
X Incorrect. The synthesis above used bromobutane, but acetylene is the only allowed source of carbon...
X Incorrect. The synthesis above used bromobutane, but acetylene is the only allowed source of carbon atoms. Using the reagents given, identify a synthetic route for the production of bromobutane from acetylene. ? H Br The transformation above can be performed with some reagent or combination of the reagents listed below. Give the necessary reagent(s) in the correct order, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct solution, provide...
11. (10 pts) Give reagents and specific reaction conditions for D through Mthat would result in...
11. (10 pts) Give reagents and specific reaction conditions for D through Mthat would result in the provided chemical transformations, OH OEt R-R R-R Х Х D E F G RC( OH ROH R=R H I J K L RH RX M CO2 ANSWERS D E J F K G L H M
tylphenylmethanol from benzaldehyde (Ph-CHO) (g) cyclopentylphenylm ctan-1-ol from 1-bromohexane (h) octan-1-olf ou would accomplish the following...
tylphenylmethanol from benzaldehyde (Ph-CHO) (g) cyclopentylphenylm ctan-1-ol from 1-bromohexane (h) octan-1-olf ou would accomplish the following transformations. You may use any additional reagents you ne Show how you would ac A (b) SO3 CH.CH,CH; H OH (racemic) OH O о OH CI_cuci (e) CH, --C-CH2CH2-C-OCH,CH, → CH-CH-CH,CH, ---OCH,CH, O o OH OH ) CH-C-CH.CH-C-OCH,CH, - CH -CH-CH2CH.-CH, Show how you would synthesize the following: Prenylethanol by the addition of formaldehyde to a suitable Grignard reagent D 2-phenylethanol from a suitable...
Practice Problem 22.46b Identify how you would make hexylamine from 1-bromopentane: Br Choose from the following...
Practice Problem 22.46b Identify how you would make hexylamine from 1-bromopentane: Br Choose from the following list of reagents: "NH2 А B с D NaN3 NaCN 03 PBr3 E F G H xs LAIHA (H+), NaBH, CN NH3 DMS H20 Reagent 1: Reagent 2: Reagent 3: Ounctie
a. Alkenes with electron withdrawing groups are good dienophiles-True/False b. Wolfkishner reaction is helpful to convert an ester to alkane. True false c. Tertiary alcohol will be formed by the r...
a. Alkenes with electron withdrawing groups are good dienophiles-True/False b. Wolfkishner reaction is helpful to convert an ester to alkane. True false c. Tertiary alcohol will be formed by the reaction between a ketone and Grignard reagent True/ false d. A cyclic conjugated compound with 6 pi electron is aromatic- True/ False e. Addition of CO; to Methyl magnesium bromide is a nucleophilic addition Truel false f A good protecting group should be cleaved during the progress of the reaction-True...
+ lidt 6) How would you perform the following transformation? OCH CHE A) NaBH4 B) LiAlH4 C) 1. DIBAL-H 2. H20 D)...
+ lidt 6) How would you perform the following transformation? OCH CHE A) NaBH4 B) LiAlH4 C) 1. DIBAL-H 2. H20 D) 1. SOCI2 2. LiAlH(O-1-Bu)3 7) What reagent can be used to convert 2-methylbutan-1-ol into 2-methylbutanal? A) LiAlH4 B) Na2Cr207 C) 03 D) KMnO4 E) PCC 9) Show how you would perform the following synthesis. A) 1. 03 2. (CH3)2S B) KMnO4, cold, basic C) Os04 D) 1. mCPBA 2. potassium dichromate 25) Provide a detailed, stepwise mechanism for...
Show how you would use Grignard syntheses to prepare the following alcohols from the indicated starting...
Show how you would use Grignard syntheses to prepare the
following alcohols from the indicated starting materials and any
other necessary reagents. Draw the Grignard reagent and any other
organic reagents needed.
11 RUVIUWI Constans i Pendulu Part F Show how you would use Grignard syntheses to prepare the following alcohols from the indicated starting materials and any other necessary reagents. Draw the Grignard reagent and any other organic reagents needed. ОН -C-CH CH, from C-OCH.CH Draw the molecules on...
Select reagents from the table to show how you would carry out this transformation. If more...
Select reagents from the table to show how you would carry out
this transformation. If more than one route exists, use the one
that requires the fewest steps; in no case will more than 3 steps
be required.
Enter your selection as a series of letters for the reagents in the
order that you wish to use them, i.e. fca.
? CH2 COOH H₃C H3C a. Reagents HBr b. Mg, ether C. CO2, ether then H307 d. BH3, THF then...
just yellow question
< Back Homework Chapter 16 16.33 Show how you would convert benzaldehyde into cach of the following. You may use any other needed reagents, and more than one step may be required. (a) Benzyl alcohol (F) 3-Methyl-1-phenyl-1-butanol (k) CHCHDOH (b) Benzoic acid (g) Benzyl bromide (1) CH.CH(OH)CN (c) Benzoyl chloride (h) Toluene (m) CHECHNOH (d) Benzophenone (i) CH CH(OCH (n) CHECHNNHCHE (e) 1-Phenylethanol G) CH.CH (o) C.H.CHCHCHCH, 16.36 Give structures for compounds A-E. Cyclohexanol in A (CHO)...
Problem 16.33 Show how you would convert benzaldehyde into each of the compounds using the reagents (A - G) in the table below where necessary. H20+ PBrz NaBH4 A: (1) AICI: (2) H307 SOCI2 Ag(NH3)2 NHz/H20 B: C: D: LiAIH4 E: F: G: X Incorrect. (c) C6H5CHENNHC6H5 + CH stereoisomer (E)-1-phenyl-2-(phenylmethylidene)hydrazine A: PPhz Edit H3C X Incorrect. (d) CGHSCH=CHCH=CH2 H B (a Wittig reagent) B: ? Edit Problem 16.49 Compounds W and X are isomers; they have the molecular formula...
X Incorrect. The synthesis above used bromobutane, but acetylene is the only allowed source of carbon atoms. Using the reagents given, identify a synthetic route for the production of bromobutane from acetylene. ? H Br The transformation above can be performed with some reagent or combination of the reagents listed below. Give the necessary reagent(s) in the correct order, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct solution, provide...
11. (10 pts) Give reagents and specific reaction conditions for D through Mthat would result in the provided chemical transformations, OH OEt R-R R-R Х Х D E F G RC( OH ROH R=R H I J K L RH RX M CO2 ANSWERS D E J F K G L H M
tylphenylmethanol from benzaldehyde (Ph-CHO) (g) cyclopentylphenylm ctan-1-ol from 1-bromohexane (h) octan-1-olf ou would accomplish the following transformations. You may use any additional reagents you ne Show how you would ac A (b) SO3 CH.CH,CH; H OH (racemic) OH O о OH CI_cuci (e) CH, --C-CH2CH2-C-OCH,CH, → CH-CH-CH,CH, ---OCH,CH, O o OH OH ) CH-C-CH.CH-C-OCH,CH, - CH -CH-CH2CH.-CH, Show how you would synthesize the following: Prenylethanol by the addition of formaldehyde to a suitable Grignard reagent D 2-phenylethanol from a suitable...
Practice Problem 22.46b Identify how you would make hexylamine from 1-bromopentane: Br Choose from the following list of reagents: "NH2 А B с D NaN3 NaCN 03 PBr3 E F G H xs LAIHA (H+), NaBH, CN NH3 DMS H20 Reagent 1: Reagent 2: Reagent 3: Ounctie
a. Alkenes with electron withdrawing groups are good dienophiles-True/False b. Wolfkishner reaction is helpful to convert an ester to alkane. True false c. Tertiary alcohol will be formed by the reaction between a ketone and Grignard reagent True/ false d. A cyclic conjugated compound with 6 pi electron is aromatic- True/ False e. Addition of CO; to Methyl magnesium bromide is a nucleophilic addition Truel false f A good protecting group should be cleaved during the progress of the reaction-True...
+ lidt 6) How would you perform the following transformation? OCH CHE A) NaBH4 B) LiAlH4 C) 1. DIBAL-H 2. H20 D) 1. SOCI2 2. LiAlH(O-1-Bu)3 7) What reagent can be used to convert 2-methylbutan-1-ol into 2-methylbutanal? A) LiAlH4 B) Na2Cr207 C) 03 D) KMnO4 E) PCC 9) Show how you would perform the following synthesis. A) 1. 03 2. (CH3)2S B) KMnO4, cold, basic C) Os04 D) 1. mCPBA 2. potassium dichromate 25) Provide a detailed, stepwise mechanism for...
Show how you would use Grignard syntheses to prepare the
following alcohols from the indicated starting materials and any
other necessary reagents. Draw the Grignard reagent and any other
organic reagents needed.
11 RUVIUWI Constans i Pendulu Part F Show how you would use Grignard syntheses to prepare the following alcohols from the indicated starting materials and any other necessary reagents. Draw the Grignard reagent and any other organic reagents needed. ОН -C-CH CH, from C-OCH.CH Draw the molecules on...
Select reagents from the table to show how you would carry out
this transformation. If more than one route exists, use the one
that requires the fewest steps; in no case will more than 3 steps
be required.
Enter your selection as a series of letters for the reagents in the
order that you wish to use them, i.e. fca.
? CH2 COOH H₃C H3C a. Reagents HBr b. Mg, ether C. CO2, ether then H307 d. BH3, THF then...
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