4) Write the product, and draw a complete curved arrow mechanism for the reaction below. Include...
34 2h H-NMR Spectrum of Ester A НЕ НЕ на PPM tr H-NMR Spectrum of Product B НЕ зН зн на НL 0 PPM ) Write a comple te curved arrow mechanism for the bromination reaction below. Include the formation of all intermediates (10 points). нооно а 5) Name the following molecules (8 points total). но, (q 6) When an ester A is treated with one equivalent of sodium methoxide, product B is formed. The 'H-NMR spectra of A and...
4) Write the product, and draw a complete curved arrow mechanism for the reaction below. Include the formation of all intermediates (10 points total) Product: NA Mochanism :N -z-
B. Using curved arrow notation, draw the reaction mechanism and predict the product the reaction below. Show all reaction intermediates and account for stereochemical requirements. [6 MARKS) EtOna / EtOH ? OTS Heat
please provide detailed explanation of solution for thumbs up 6. Reaction Coordinate Diagrams (10 points) (a) Sketch an accurate energy diagram that meets the following criteria (4 points) SM - OM Int - P SM - Int is endergonic and the slowest step. overall SM + P is exergonic. al Free Energy (G) Reaction Coordinate (b) Label the transitions states in your diagram (2 points) (c) Indicate AG. for the overall transformation (2 points) (d) Indicate E. for each step...
Draw the major product of this reaction & a complete curved arrow mechanism and explain why the observed product is formed. H-Br
4 4) Write the reaction product and use the curved arrow notation to draw a mechanism that accounts for the formation of product upon oxymercuration/ reduction of cis-4-hexenoic acid in aqueous THF. (8 points) a) Write the reaction. 1) Hg(OAC), aq, THE 2) NaBH, aq. THE HO cis-4-hextenoic acid b) Write a mechanism.
7. The following two reactions proceed through an Su2 mechanism. Determine the likely product for each and match the 1H NMR spectrum below to the product of one of the reactions, Show your assignments for ALL NMR peaks to explain your conclusions ,KcOs OH DMF CHy-l, KCO ON он DMF зн 1H 1H 2H 9 8 5 PPM 0 Зн 2H 2H 2H 0 PРM Page 4
(2 pts) Show the complete mechanism using curved arrow formalism for the reaction of 4-ethyl-1-cyclohexanecarboxaldehyde treated with ethylene glycol in acid. Provide the 1H and 13C NMR data for the product formed in Question #1. Report the 1H NMR data in the sequence: chemical shift, integration, multiplicity (e.g. d 1.0, 3H, triplet). Be sure to clearly label which proton and carbon you are reporting.
MASS SPECTRUM 100 80- m/z 150 60 40 0.2 20. 00 1000 4500 2500 2000 150) 000 3500 3000 0.0+ 0.0 Wavenurbers (cm-1) on 160 40 120 13C NMR 2 peaks overlapping 100 20 40 120 60 80 PPM 140 6H H NMR 2H 2H 2H 1H 1H 2 7 5 8 PPM 1. Using the spectra on the next page, solve for the structure of an unknown organic compound. Fòi full credit (and consideration for partial credit) show your...
Draw a curved arrow mechanism for the following acid-catalyzed isomerization reaction. You must show all intermediates. (10 points) H H H20